Kinetics of Cell Carbohydrates - Sonal Choubey - Books - LAP Lambert Academic Publishing - 9786203465396 - March 3, 2021
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Sonal Choubey
Kinetics of Cell Carbohydrates

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The kinetics of uncatalysed and catalysed oxidation of D-ribose by Cerium(IV) has been studied in acidic medium in the temperature range 303-338 K. The reaction has been found to be first order with respect to [D-ribose] in both uncatalysed and catalysed reactions. The rates follow first order kinetics in [Ir(III)] catalysed oxidation reaction. The effect of [HSO4- ] has also been observed. The increase in ionic strength of the medium decreases the rate of uncatalysed reaction while increases catalysed reaction. A 1:2 stoichiometry is observed in the oxidation. From the effect of temperature on the reaction rate, the Arrhenius and activation parameters have been calculated. A suitable mechanism has been proposed and a rate law explaining the experimental results is derived.

Media Books     Paperback Book   (Book with soft cover and glued back)
Released March 3, 2021
ISBN13 9786203465396
Publishers LAP Lambert Academic Publishing
Pages 92
Dimensions 152 × 229 × 6 mm   ·   155 g
Language English  

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