Stabil'nye Radikaly V Reaktsii Polimerizatsii: Kinetika I Mekhanizm - Nikolay Kozhevnikov - Books - Palmarium Academic Publishing - 9783639845150 - September 12, 2014
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Nikolay Kozhevnikov
Stabil'nye Radikaly V Reaktsii Polimerizatsii: Kinetika I Mekhanizm Russian edition

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Issledovano vliyanie nekotorykh neytral'nykh i zaryazhennykh stabil'nykh radikalov na polimerizatsiyu vinilovykh monomerov v bloke i v rastvore. Na osnove kineticheskikh (dilatometriya) i spektral'nykh issledovaniy (elektronnaya spektroskopiya, spektroskopiya elektronnogo paramagnitnogo rezonansa), a takzhe s privlecheniem literaturnykh dannykh predlozheny mekhanizmy izuchennykh reaktsiy, naydeny ikh kolichestvennye kharakteristiki. Pokazano, chto nitroksil'nye stabil'nye radikaly (aromaticheskie i iminoksil'nye) ingibiruyut radikal'nuyu polimerizatsiyu po slozhnomu mekhanizmu, zavisyashchemu ot prirody ingibitora i initsiatora. Anion-radikaly tetratsiankhinodimetana takzhe ingibiruyut polimerizatsiyu, no s nekotorymi peroksidnymi initsiatorami oni obrazuyut initsiiruyushchuyu sistemu i uskoryayut protsess. Sushchestvennoe vliyanie na eti reaktsii okazyvayut svoystva i kontsentratsiya reagentov, monomera, rastvoritelya. Dlya nauchnykh rabotnikov, studentov, spetsializiruyushchikhsya v oblasti fiziko-khimii polimerov.

Media Books     Paperback Book   (Book with soft cover and glued back)
Released September 12, 2014
ISBN13 9783639845150
Publishers Palmarium Academic Publishing
Pages 88
Dimensions 152 × 229 × 5 mm   ·   149 g
Language German  

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